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81.
《Ceramics International》2022,48(17):24157-24191
Great progress in the development of low-cost ceramic membranes from alternative materials have been achieved recently towards various application especially water and wastewater treatment. However, their significance has not been fully recognized and understood especially in term of their microstructural analysis such as formation of grain growth and microcracks. This review paper summarizes fabrication method, alternative materials, microstructure, wettability, mechanical properties and application of low-cost ceramic membrane. The fabrication method including slip casting, tape casting, extrusion, pressing method and phase inversion technique are described. Alternative materials used in low-cost ceramic membrane fabrication are discussed and categorized into clays, agricultural waste, industrial waste and animal bone waste. The mechanisms of morphology formation, microstructure and wettability properties are analysed. Modification strategies for the surface of low-cost ceramic membrane are discussed, and classified into modification for separation application, modification for photocatalytic application and modification for membrane distillation and membrane contactor system. Modification improves the membrane structure by changing the pore size, porosity and wettability properties of low-cost ceramic membranes. Mechanical properties of low-cost ceramic membranes are also discussed in detail towards several mechanism, like grain growth phenomenon and formation of microcracks which also considered as membrane defects. Grain growth phenomenon can be divided into normal and abnormal grain growth. Meanwhile, formation of microcracks could be occurred in single-phase polycrystalline ceramics that have anisotropic grains or biphasic polycrystalline grains. The application of low-cost ceramic membrane in seawater desalination, oily wastewater treatment, heavy metal adsorption, textile separation and photocatalytic application are reviewed. Finally, some possible opportunities and challenges for further development of low-cost ceramic membrane are pointed out. 相似文献
82.
Upconversion phosphors are known as a material system that can convert near-infrared light into visible/ultraviolet emissions by sequentially absorbing multiple photons. The studies on upconversion materials often use two rare earth (RE) ions as a sensitizer-activator pair. We investigated the influences on luminescence intensity depending on Cr-doping content (x) of hexagonal NaLu0.98–xCrxF4Er0.02 (x = 0–0.9) upconversion material by substituting Lu3+ ions with Cr3+in the absence of Gd3+. The change in upconversion luminescence intensity appears with saddle-like shape. We suggest that Cr3+ ions play the dual role as a constituent in host lattice and a sensitizer in the upconversion process. Optimal conditions for gaining the strongest upconversion emission correspond to x = 0.3–0.5, where there are effective energy transfers between Cr3+ and Er3+ ions and CrEr dimers. Apart from these values, the emission intensity decreases rapidly which can be ascribed to the absence of multiple-photon absorption for the case of low Cr3+ contents, and to the coupling between Cr3+ and/or Er3+ ions for the case of high Cr3+ contents. Magnetization and electron-spin-resonant measurements were performed to understand the correlation between the optical and magnetic properties. 相似文献
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85.
《International Journal of Hydrogen Energy》2019,44(2):587-593
A solid-state photoelectrochemical (SSPEC) cell is an attractive approach for solar water splitting, especially when it comes to monolithic device design. In a SSPEC cell the electrodes distance is minimized, while the use of polymer-based membranes alleviates the need for liquid electrolytes, and at the same time they can separate the anode from the cathode. In this work, we have made and tested, firstly, a SSPEC cell with a Pt/C electrocatalyst as the cathode electrode, under purely gaseous conditions. The anode was supplied with air of 80% relative humidity (RH) and the cathode with argon. Secondly, we replaced the Pt/C cathode with a photocathode consisting of 2D photocatalytic g-C3N4, which was placed in tandem with the photoanode (tandem-SSPEC). The tandem configuration showed a three-fold enhancement in the obtained photovoltage and a steady-state photocurrent density. The mechanism of operation is discussed in view of recent advances in surface proton conduction in absorbed water layers. The presented SSPEC cell is based on earth-abundant materials and provides a way towards systems of artificial photosynthesis, especially for areas where water sources are scarce and electrical grid infrastructure is limited or nonexistent. The only requirements to make hydrogen are humidity and sunlight. 相似文献
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Chung-Ya Tsao Wei-Hsing Tuan Kuei-Chih Feng 《International Journal of Applied Ceramic Technology》2019,16(5):2094-2100
In this study, relationships between the processing, microstructure, and properties of barium niobate (Ba5Nb4O15) are investigated. The milling of a Ba5Nb4O15 powder in water is effective with respect to size reduction. However, after milling in water, BaCO3 is formed within the slurry. With the increase in the amount of BaCO3 formed, the aspect ratio of the elongated Ba5Nb4O15 grains increases. The formation of the elongated Ba5Nb4O15 grains prohibits the densification. Hence, the microwave dielectric properties, including permittivity and quality factor, are poor because of the low density. In addition, milling in ethanol is carried out for comparison: A lower amount of BaCO3 is formed after milling in ethanol; the extent of anisotropic grain growth is thus reduced. 相似文献
89.
共价有机框架材料(COFs)是一类由共价键连接的多孔晶态材料。因具有单体链接方式灵活、结构可调、活性位点丰富、比表面积大、理化性质相对稳定等特点,它们在气体储存与分离、能量储存、催化和光电学领域受到了广泛的关注。本文主要从结构设计、合成方法及功能化、材料的分析表征和晶形控制等方面概括地介绍了COFs材料。在此基础上,综述了COFs材料在关键核素分离方面的研究进展,并展望了其在核素分离领域的应用前景和今后的研究方向。 相似文献
90.
Prof. Dr.‐Ing. Falk Jaeger 《Mauerwerk》2019,23(1):50-54
Brick masonry is not only a question of building physics, building construction and durability, i.e. sustainability, but has much to do with aesthetics and making sense, which may have been forgotten in modern architecture with its absolute lack of décor. Masonry as an art form has been scarce since the era of brick expressionism. Recently, there have been some exceptions – and thoroughly welcome. The ”Fjordenhus“ in Vejle, Denmark, is an astonishing example. 相似文献